There is no actual "Fullscreen"/Large Album Art option available on Windows Desktop 22.214.171.1243.geb9254e9 as of October 8th, 2019. As it currently stands Spotify's design is no better than a windows file explorer list-view.
Updated on 2019-10-10
Nice idea! Marked as a new idea and edited the title slightly to make it easier to find via search :)
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