I'm quite sad. My favorait song (Papaoutai) from the new Pentatonix Vol.3 got blocked overnight. It was playing fine for the last few days since the album was released, but last night it was deleted from my computer and library. Is there any way to know what happed?
Missing or unavailable music is almost always a decision by the artist/label to withhold the content from Spotify. Sometimes it's temporarily unavailable while they sort out legal issues or correct metadata, in which case it'll be back up as soon as they resubmit it to Spotify.
While it might be a good idea to contact the label directly and ask why the music isn't on Spotify, you can also fill out this form to let Spotify staff know of your interest.