When you say cannot be played, is it not there or does it error out? If so what's the error?
What region are you in?
Please note that for Spotify to have music on their servers; they require the permissions from the record label. The chances are that the record label have not given the permissions to Spotify, which means that Spotify can't have the music yet. Spotify make everything they have available to us, so hopefully it will appear soon! Hate to break it to you, but if it isn't available then that is why and there's nothing that anyone can do to change the fact.
You can also check out the Music FAQ which has some more information.
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